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Investigation of Hydrologic and Biogeochemical Controls on Arsenic Mobilization Using Distributed Sensing at a Field Site in Munshiganj, Bangladesh

Abstract

The presence of arsenic in the groundwater has led to the largest environmental poisoning in history; tens of millions of people in the Ganges Delta continue to drink groundwater that is dangerously contaminated with arsenic. A current working hypothesis is that arsenic is mobilized in the near surface environment where sediments are weathered by seasonal changes in the redox state that drive a cycle of pyrite oxidation and iron oxide reduction. In order to test the supporting hypothesis that subsurface geochemical changes may be induced by agricultural activity, we deployed 42 wirelessly networked ion-selective electrodes, including calcium, ammonium, nitrate, ORP, chloride, carbonate, and pH in a rice paddy in the Munshiganj district of Bangladesh in January of 2006. Each sensor was connected to an MDA300 sensor board and Mica2 wireless transceiver and computational device. Over a period of 11 days, we observed clear diel, and diurnal trends in 4 of the electrodes (calcium, ammonium, chloride and carbonate). The trends may be due to hydrological changes, or geochemical changes induced either by photosynthesis in the overlying water (which then infiltrated to the depth of the sensors) or in the root zone of rice plants. While the spatiotemporally dense measurements from wireless sensor networks enable scientists to ask new questions and elucidate complex relationships in heterogeneous physical environments such as soil, there are many practical issues to address in order to collect data usable for scientific purposes. For example, in response to a stream of faults in one of our sensor network deployments, we designed Sympathy to enable users to find and fix problems impacting the quantity of data collected in the field. Sympathy detects packet loss experienced at the base station and systematically assigns blame to faulty components in the network for remediation, replacing the prior policy of ad-hoc node rebooting and battery replacements. Sympathy has been deployed in many habitat monitoring sensor networks. While using Sympathy at our Bangladesh field site we received 80% of the sensor data expected at the base station, upon returning, post-deployment analysis revealed that 42% of these sensor data were potentially faulty. Due to the remote location of the deployment, we were unable to go back and validate the questionable segments of the data set, forcing us to discard potentially interesting information. In addition to being undesirable, this response is often avoidable as well. Even simple actions such as checking sensor connections and quickly validating sensors in the field could have increased our confidence in the quality of the data, minimizing doubts that data observations were simply caused by badly behaving hardware. To improve data quality, we have designed a system called Confidence, which continuously monitors data collected at a base-station to identify faulty data and notify the user in the field of actions they can take to validate the data or remediate the sensor fault. Augmenting a sensor network deployment with Confidence and Sympathy enables users in the identification and remediation of faults impacting the quality and quantity of data respectively.

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