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A decarboxylative approach for regioselective hydroarylation of alkynes

2016

Zhang, Jing;
Shrestha, Ruja;
Hartwig, John F.;
Zhao, Pinjing

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A decarboxylative approach for regioselective hydroarylation of alkynes
Results and discussion
Methods
Figure 1 Strategies for catalytic alkyne hydroarylation and the resulting regiochemistry.
Figure 2 Model reaction for the catalyst development of decarboxylative alkyne hydroarylation.
Figure 3 Proposed divergent reactivity of a cyclometallated alkenylruthenium(II) carboxylate intermediate.
Figure 4 Mechanism-guided efforts towards catalyst improvement.
Table 1 Decarboxylative alkyne hydroarylation with ortho- and para-benzoic acids.
Table 2 Product selectivity when using meta-benzoic acids and differentially substituted alkynes.
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