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Nanoporous gold assemblies of calixarene-phosphine-capped colloids
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https://doi.org/10.1039/c7cc05116fAbstract
The synthesis of high surface-area colloidal assemblies of calixarene-phosphine-capped nanoporous gold is reported under reductive electrochemical conditions. These materials uniquely exhibit a remarkably thin wall thickness down to 10 nm, while possessing pore sizes on the order of up to hundreds of nanometers, which can be controlled via choice of organic ligand.
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