Hexane‐soluble derivatives of neodymium amide Nd‐(NMe2)3 such as 1 or the unsolvated heterometallic peralkyl compound 2 form in the reaction of MMe3 (M = Al, Ga) with 3. This provides a route to soluble lanthanide complexes with small ligands. (Formula Presented.) (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany