With the intent to gain further knowledge on the spectral structures and statistical regularities of surface atmospheric chemistry, the chemical gases (NO, NO2, NOx, CO, SO2, and O3) and aerosol (PM10) measured at 74 air quality monitoring stations over the island of Taiwan are analyzed for the year of 2004 at hourly resolution. They represent a range of surface air quality with a mixed combination of geographic settings, and include urban/rural, coastal/inland, plain/hill, and industrial/agricultural locations. In addition to the well-known semi-diurnal and diurnal oscillations, weekly, and intermediate (20 ∼ 30 days) peaks are also identified with the continuous wavelet transform (CWT). The spectra indicate power-law scaling regions for the frequencies higher than the diurnal and those lower than the diurnal with the average exponents of and 1, respectively. These dual-exponents are corroborated with those with the detrended fluctuation analysis in the corresponding time-lag regions. These exponents are mostly independent of the averages and standard deviations of time series measured at various geographic settings, i.e., the spatial inhomogeneities. In other words, they possess dominant universal structures. After spectral coefficients from the CWT decomposition are grouped according to the spectral bands, and inverted separately, the PDFs of the reconstructed time series for the high-frequency band demonstrate the interesting statistical regularity, 3 power-law scaling for the heavy tails, consistently. Such spectral peaks, dual-exponent structures, and power-law scaling in heavy tails are important structural information, but their relations to turbulence and mesoscale variability require further investigations. This could lead to a better understanding of the processes controlling air quality. © 2011 Author(s).