A mass budget was constructed for organic carbon on the upper slope of the Middle Atlantic Bight, a region thought to serve as a depocenter for fine-grained material exported from the adjacent shelf. Various components of the budget are internally consistent, and observed differences can be attributed to natural spatial variability or to the different time scales over which measurements were made. The flux of organic carbon to the sediments in the core of the depocenter zone, at a water depth of ∼1000 m, was measured with sediment traps to be ∼65 mg C m-2 day-1, of which 6-24 mg C m-2 day-1 is buried. Oxygen fluxes into the sediments, measured with incubation chambers attached to a free vehicle lander, correspond to total carbon remineralization rates of 49-70 mg C m-2 day-1. Carbon remineralization rates estimated from gradients of Corg within the mixed layer, and from gradients of dissolved ammonia and phosphate in pore waters, sum to only ∼4-6 mg C m-2 day-1. Most of the Corg remineralization in slope sediments is mediated by bacteria and takes place within a few mm of the sediment-water interface. Most of the Corg deposited on the upper slope sediments is supplied by lateral transport from other regions, but even if all of this material were derived from the adjacent shelf, it represents <2% of the mean annual shelf productivity. This value is further lowered by recognizing that as much as half of the Corg deposited on the slope is refractory, having originated by reworking from older deposits. Refractory Corg arrives at the sea bed with an average 14C age 600-900 years older than the pre-bomb 14C age of DIC in seawater, and has a mean life in the sediments with respect to biological remineralization of at least 1000 years. Labile carbon supplied to the slope, on the other hand, is rapidly and (virtually) completely remineralized, with a mean life of < ∼ 1 year. Carbon-14 ages of fine-grained carbonate and organic carbon present within the interstices of shelf sands are consistent with this material acting as a source for the old carbon supplied to the slope. Winnowing and export of reworked carbon may contribute to the often-described relationship between organic carbon preservation and accumulation rate of marine sediments. © 1994.

Concentrations of U, Th, 231Pa and 10Be were measured in Holocene sediments from two cores collected off the west coast of South America, two cores from the East Pacific Rise, two from the equatorial Pacific and one from the south Pacific central gyre. Our results, together with data from 5 cores reported in the literature, show that boundary scavenging plays a major role in the removal of 10Be from the Pacific Ocean. Deposition rates of 10Be at three margin sites are more than an order of magnitude greater than at sites of red clay accumulation in the deep central Pacific. Deposition of 231Pa is 4 to 5-fold greater at the margin sites. The residence time of 10Be with respect to chemical scavenging, defined as its inventory in the water column divided by its rate of removal to the sediments, varies regionally from > 1000 years at the red-clay sites in the deep central Pacific to ∼ 100 years at the margin sites. Different factors control boundary scavenging of Pa and Be. For example, scavenging of 231Pa is enhanced by metal-oxide coatings of particles, whereas this seems to have little influence on the scavenging of 10Be. © 1990.

BERYLLIUM-10 (half-life 1.5 Myr) is produced by spallation of nitrogen and oxygen atoms by cosmic rays in the upper atmosphere. Its production rate is proportional to the flux of cosmic rays, which is modulated by solar activity and the strength of the Earth's magnetic field1,2. Weakening of the magnetic field allows more cosmic rays to impinge on the Earth's atmosphere, thereby increasing 10Be production. Here we report that the ocean-wide average accumulation rate of 10Be in Pacific sediments, which reflects the global average production rate of 10Be (ref. 3), was at least 25% greater during the height of the most recent ice age (∼ 24,000-16,000 yr ago) than during the Holocene (the past 10,000 yr). The higher production rate of 10Be records the lower intensity of the geomagnetic field during that period and is consistent with the hypothesis developed to explain the younger 14C ages of fossil corals compared with ages obtained by U-Th dating4. These results also point to a more general need to consider variations in production rate in geochronological studies using other cosmogenic nuclides. © 1992 Nature Publishing Group.

THE Black Sea is the largest anoxic marine basin in the world today1. Below the layer of oxygenated surface water, hydrogen sulphide builds up to concentrations as high as 425 μM in the deep water down to a maximum depth of 2,200 m (ref. 2). The hydrographic regime is characterized by low-salinity surface water of river origin overlying high-salinity deep water of Mediterranean origin1,3. A steep pycnocline, centred at about 50 m is the primary physical barrier to mixing and is the origin of the stability of the anoxic (oxygen/hydrogen sulphide) interface. Here we report new observations, however, that indicate dramatic changes in the oceanographic characteristics of the anoxic interface of the Black Sea over decadal or shorter timescales. The anoxic, sulphide-containing interface has moved up in the water column since the last US cruises in 1969 and 1975. In addition, a suboxic zone overlays the sulphide-containing deep water. The expected overlap of oxygen and sulphide was not present. We believe that these observations result from horizontal mixing or flushing events that inject denser, saltier water into the relevant part of the water column. It is possible that man-made reduction in freshwater inflow into the Black Sea could cause these changes, although natural variability cannot be discounted. © 1989 Nature Publishing Group.

Changing climate conditions affect dust emissions and the global dust cycle, which in turn affects climate and biogeochemistry. In this study we use observationally constrained model reconstructions of the global dust cycle since the Last Glacial Maximum, combined with different simplified assumptions of atmospheric and sea ice processing of dust-borne iron, to provide estimates of soluble iron deposition to the oceans. For different climate conditions, we discuss uncertainties in model-based estimates of atmospheric processing and dust deposition to key oceanic regions, highlighting the large degree of uncertainty of this important variable for ocean biogeochemistry and the global carbon cycle. We also show the role of sea ice acting as a time buffer and processing agent, which results in a delayed and pulse-like soluble iron release into the ocean during the melting season, with monthly peaks up to ~17 Gg/month released into the Southern Oceans during the Last Glacial Maximum (LGM).

Deposition of continental mineral aerosols (dust) in the Eastern Tropical North Atlantic Ocean, between the coast of Africa and the Mid-Atlantic Ridge, was estimated using several strategies based on the measurement of aerosols, trace metals dissolved in seawater, particulate material filtered from the water column, particles collected by sediment traps and sediments. Most of the data used in this synthesis involve samples collected during US GEOTRACES expeditions in 2010 and 2011, although some results from the literature are also used. Dust deposition generated by a global model serves as a reference against which the results from each observational strategy are compared. Observation-based dust fluxes disagree with one another by as much as two orders of magnitude, although most of the methods produce results that are consistent with the reference model to within a factor of 5. The large range of estimates indicates that further work is needed to reduce uncertainties associated with each method before it can be applied routinely to map dust deposition to the ocean. Calculated dust deposition using observational strategies thought to have the smallest uncertainties is lower than the reference model by a factor of 2-5, suggesting that the model may overestimate dust deposition in our study area.This article is part of the themed issue 'Biological and climatic impacts of ocean trace element chemistry'.