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Open Access Publications from the University of California

Scholarly Works (4 results)

  • Article
  • Peer Reviewed
UC Berkeley Previously Published Works (2017)

Purpose

Hydrogen sulfide (H2S) is a highly toxic gas with well-established, acute irritation effects on the eye. The population of Rotorua, New Zealand, sited on an active geothermal field, has some of the highest ambient H2S exposures in the world. Evidence from ecological studies in Rotorua has suggested that H2S is associated with cataract. The purpose of the present study was, using more detailed exposure characterization, clinical examinations, and anterior eye photography, to more directly investigate this previously reported association.

Methods

Enrolled were 1637 adults, ages 18 to 65, from a comprehensive Rotorua primary care medical register. Patients underwent a comprehensive ophthalmic examination, including pupillary dilation and lens photography to capture evidence of any nuclear opacity, nuclear color, and cortical and posterior subcapsular opacity. Photographs were scored for all four outcomes on the LOCS III scale with decimalized interpolation between the exemplars. H2S exposure for up to the last 30 years was estimated based on networks of passive samplers set out across Rotorua and knowledge of residential, workplace, and school locations over the 30 years. Data analysis using linear and logistic regression examined associations between the degree of opacification and nuclear color or cataract (defined as a LOCS III score ≥2.0) in relation to H2S exposure.

Results

No associations were found between estimated H2S exposures and any of the four ophthalmic outcome measures.

Conclusions

Overall, results were generally reassuring. They provided no evidence that H2S exposure at the levels found in Rotorua is associated with cataract. The previously found association between cataract and H2S exposure in the Rotorua population seems likely to be attributable to the limitations of the ecological study design. These results cannot rule out the possibility of an association with cataract at higher levels of H2S exposure.
    Cover page: Lens Opacity and Hydrogen Sulfide in a New Zealand Geothermal Area
    • Article
    • Peer Reviewed
    UC San Diego Previously Published Works (2020)

    Patterns of variability in Pleistocene magnetic susceptibility (k) from deep-sea sediment cores from the Scotia Sea show a striking similarity to patterns of dust flux recorded in the EPICA Dronning Maud Land (EDML) ice core.  Antarctic marine k records broadly reflect the interplay of lithogenic sediment provenance, biological productivity, sediment transport processes, and post-depositional diagenesis. Here we explore the origin of the Scotia Sea k record via a detailed rock magnetic study across the transition from MIS 6 to MIS 5. We analyzed bulk sediment and grain size separates in order to construct magnetic signatures of iceberg rafted debris (IBRD), sortable silt, and eolian input. The MIS 6-MIS 5 transition consists of three lithologies, a high k silty-clay-rich diatomaceous mud deposited during the glacial interval, an IBRD-rich but low k silty clay that marks the onset of deglaciation, and a low k diatomaceous ooze in which IBRD decreases forward through time. The high k glacial sediment is characterized by multi-domain hysteresis parameters, low χARM/χ values, S ratios near 1, and thermomagnetic curves indicative of low-Ti titanomagnetite. The absence of k peaks in the IBRD-rich silty-clay and IBRD rich diatomaceous ooze likely reflects the weakly magnetic lithogenic detritus supplied by Weddell Sea Embayment (WSE) ice streams, such as sandstone, quartzite, metasedimentary lithologies, phyllite and schist observed in lateral moraines adjacent to ice streams of the eastern WSE. The deglacial interval is characterized by elevated MR/MS, χARM/χ, and HIRM values, and decreased S-ratios in the bulk sediment, suggesting a greater proportion of high coercivity minerals such as hematite or goethite in the iron oxide assemblage. Preliminary data from grain size separates indicates that the clay mass fraction is > 0.5 in all three lithologies. Clay is also the dominant size fraction in the EDML ice core dust, with particle sizes generally < 5 μm. The Scotia Sea clay fraction k values are a factor 1.5 to 5 weaker than the silt fraction k values, and therefore are not the main carrier of the bulk k signal. The rock magnetic signatures of Scotia Sea sediment will be compared to those of terrestrial till and bedrock from the WSE, and to those of potential dust sources in South America to identify the sediment sources and environmental processes responsible for the k signal.

      • Article
      • Peer Reviewed
      UC San Diego Previously Published Works (2021)
        Cover page: Miocene to present oceanographic variability in the Scotia Sea and Antarctic ice sheets dynamics: Insight from revised seismic-stratigraphy following IODP Expedition 382
        • Article
        • Peer Reviewed
        UC San Diego Previously Published Works (2022)
        Ice loss in the Southern Hemisphere has been greatest over the past 30 years in West Antarctica. The high sensitivity of this region to climate change has motivated geologists to examine marine sedimentary records for evidence of past episodes of West Antarctic Ice Sheet (WAIS) instability. Sediments accumulating in the Scotia Sea are useful to examine for this purpose because they receive iceberg-rafted debris (IBRD) sourced from the Pacific- and Atlantic-facing sectors of West Antarctica. Here we report on the sedimentology and provenance of the oldest of three cm-scale coarse-grained layers recovered from this sea at International Ocean Discovery Program Site U1538. These layers are preserved in opal-rich sediments deposited ∼1.2 Ma during a relatively warm regional climate. Our microCT-based analysis of the layer's in-situ fabric confirms its ice-rafted origin. We further infer that it is the product of an intense but short-lived episode of IBRD deposition. Based on the petrography of its sand fraction and the Phanerozoic 40Ar/39Ar ages of hornblende and mica it contains, we conclude that the IBRD it contains was likely sourced from the Weddell Sea and/or Amundsen Sea embayment(s) of West Antarctica. We attribute the high concentrations of IBRD in these layers to "dirty" icebergs calved from the WAIS following its retreat inland from its modern grounding line. These layers also sit at the top of a ∼366-m thick Pliocene and early Pleistocene sequence that is much more dropstone-rich than its overlying sediments. We speculate this fact may reflect that WAIS mass-balance was highly dynamic during the ∼41-kyr (inter)glacial world.
          Cover page: Episodes of Early Pleistocene West Antarctic Ice Sheet Retreat Recorded by Iceberg Alley Sediments
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