Ammonia is a promising energy and hydrogen carrier due to its ease of liquification, high hydrogen content, and potential to be synthesized without carbon feedstocks. Despite its widespread use in agriculture, the utilization of ammonia to deliver hydrogen or for direct power generation is still under development. Sometimes referred to as “cracking”, the standard approach for recovering hydrogen from ammonia relies on harsh reaction conditions that limit its suitability for low-carbon transitions. This work investigates the technology development status and potential cost of plasma and electrolysis-based ammonia decomposition, benchmarks them with thermal-chemical decomposition, and further compares them with direct ammonia-to-power solid oxide fuel cell systems. Results suggest that in order to reach cost parity with cracking technologies, plasma-based decomposition must achieve one order of magnitude improvement in energy efficiency (to 10 kWh/kg or lower), while electrolysis decomposition must achieve enhanced durability using cheap electrolytes.

Hydrogen is pivotal in the transition to sustainable energy systems, playing major roles in power generation and industrial applications. Metal–organic frameworks (MOFs) have emerged as promising mediums for efficient hydrogen storage. However, identifying potential candidates for deployment is challenging due to the vast number of currently available synthesized MOFs. This study integrates molecular simulations, machine learning, and techno-economic analysis to evaluate the performance of MOFs across broad operation conditions for hydrogen storage applications. While previous screenings of MOF databases have predominantly emphasized high hydrogen capacities under cryogenic conditions, this study reveals that optimal temperatures and pressures for cost minimization depend on the raw price of the MOF. Specifically, when MOFs are priced at $15/kg, among the 9720 MOFs tested, 9692 MOFs achieve the lowest cost at temperatures between 170 K and 250 K and a pressure of 150 bar. Under these optimal conditions, 362 MOFs deliver a lower levelized cost of storage than 350 bar compressed gas hydrogen storage. Furthermore, this study reveals key material properties that result in low system cost, such as high surface areas (>3000 m2/g), large void fractions (>0.78), and large pore volumes (>1.1 cm3/g).

Food waste makes up approximately 15% of municipal solid waste generated in the United States, and 95% of food waste is ultimately landfilled. Its bioavailable carbon and nutrient content makes it a major contributor to landfill methane emissions, but also presents an important opportunity for energy recovery. This paper presents the first detailed analysis of monthly food waste generation in California at a county level, and its potential contribution to the state's energy production. Scenarios that rely on excess capacity at existing anaerobic digester (AD) and solid biomass combustion facilities, and alternatives that allow for new facility construction, are developed and modeled. Potential monthly electricity generation from the conversion of gross food waste using a combination of AD and combustion varies from 420 to 700 MW, averaging 530 MW. At least 66% of gross high moisture solids and 23% of gross low moisture solids can be treated using existing county infrastructure, and this fraction increases to 99% of high moisture solids and 55% of low moisture solids if waste can be shipped anywhere within the state. Biogas flaring practices at AD facilities can reduce potential energy production by 10 to 40%.

Substantial upscaling of carbon dioxide capture is possible in the coming decades but existing solutions for storage are projected to be limited in annual capacity by as much as 2-10 GtCO2 per year until mid-century. Temporary storage of CO2 in a solid or liquid state could prove useful for filling this gap in capacity, until more permanent and ideally lucrative CO2 sequestration options come online. There are several concepts for reversible solid-state and chemical CO2 storage, but their advantages and limitations have yet to be reviewed in this context. This article focuses on the physical and chemical aspects of CO2 storage via liquid and solid chemical carriers and sorbents, and gives an overview of the energetics around their use, as well as prospects for their future development. Exciting opportunities for coupling capture and medium to high maturity multi-year storage technologies could support carbon removal in the coming decades. Highlights of the analysis are the remarkable storage capacity of oxalic acid and formic acid (CO2-density of 1857 kg m−3 and 1152 kg m−3, compared with condensed liquid CO2 at 993-1096 kg m−3, respectively), the relative scalability and compatibility of carbonate salts for stationary storage with direct air capture, and the potential promise of multiple carriers for CO2 transportation. Solid sorbents do not achieve such ultra-high storage capacities, but could improve storage over compressed gas tanks on a capacity and energetics basis.

Digestate and biochar can be land applied to sequester carbon and improve net primary productivity, but the achievable scale is tied to expected growth in bioenergy production and land available for application. We use an attributional life-cycle assessment approach to estimate the greenhouse gas (GHG) emissions and carbon storage potential of biochar, digested solids, and composted digested solids generated from organic waste in California as a test case. Our scenarios characterize changes in organic waste production, bioenergy facility build-out, bioenergy byproduct quality, and soil response. Moderate to upper bound growth in the bioenergy sector with annual byproduct disposal over 100 years could provide a cumulative GHG offset of 50-400 MMTCO2 equiv, with an additional 80-300 MMTC sequestered in soils. This corresponds to net GHG mitigation over 100 years equivalent to 340-1500 MMTCO2 equiv (80-350% of California's annual emissions). In most scenarios, there is sufficient working land to apply all available biochar and digestate, although land becomes a constraint if the soil's rest time between applications increases from 5 to 15 years.

Materials-based H₂ storage plays a critical role in facilitating H₂ as a low-carbon energy carrier, but there remains limited guidance on the technical performance necessary for specific applications. Metal-organic framework (MOF) adsorbents have shown potential in power applications, but need to demonstrate economic promises against incumbent compressed H₂ storage. Herein, we evaluate the potential impact of material properties, charge/discharge patterns, and propose targets for MOFs' deployment in long-duration energy storage applications including backup, load optimization, and hybrid power. We find that state-of-the-art MOF could outperform cryogenic storage and 350 bar compressed storage in applications requiring ≤8 cycles per year, but need ≥5 g/L increase in uptake to be cost-competitive for applications that require ≥30 cycles per year. Existing challenges include manufacturing at scale and quantifying the economic value of lower-pressure storage. Lastly, future research needs are identified including integrating thermodynamic effects and degradation mechanisms.

Enhanced rock weathering (ERW) in soils is a promising carbon removal technology, but the realistically achievable efficiency, controlled primarily by in situ weathering rates of the applied rocks, is highly uncertain. Here we explored the impacts of coupled biogeochemical and transport processes and a set of primary environmental and operational controls, using forsterite as a proxy mineral in soils and a multiphase multi-component reactive transport model considering microbe-mediated reactions. For a onetime forsterite application of ~ 16 kg/m², complete weathering within five years can be achieved, giving an equivalent carbon removal rate of ~ 2.3 kgCO₂/m²/yr. However, the rate is highly variable based on site-specific conditions. We showed that the in situ weathering rate can be enhanced by conditions and operations that maintain high CO₂ availability via effective transport of atmospheric CO₂ (e.g. in well-drained soils) and/or sufficient biogenic CO₂ supply (e.g. stimulated plant-microbe processes). Our results further highlight that the effect of increasing surface area on weathering rate can be significant-so that the energy penalty of reducing the grain size may be justified-only when CO₂ supply is nonlimiting. Therefore, for ERW practices to be effective, siting and engineering design (e.g. optimal grain size) need to be co-optimized.