- Mukherjee, Saumya;
- Jung, Sung Won;
- Weber, Sophie F;
- Xu, Chunqiang;
- Qian, Dong;
- Xu, Xiaofeng;
- Biswas, Pabitra K;
- Kim, Timur K;
- Chapon, Laurent C;
- Watson, Matthew D;
- Neaton, Jeffrey B;
- Cacho, Cephise
Transition-metal dichalcogenides (TMDs) offer an ideal platform to experimentally realize Dirac fermions. However, typically these exotic quasiparticles are located far away from the Fermi level, limiting the contribution of Dirac-like carriers to the transport properties. Here we show that NiTe2 hosts both bulk Type-II Dirac points and topological surface states. The underlying mechanism is shared with other TMDs and based on the generic topological character of the Te p-orbital manifold. However, unique to NiTe2, a significant contribution of Ni d orbital states shifts the energy of the Type-II Dirac point close to the Fermi level. In addition, one of the topological surface states intersects the Fermi energy and exhibits a remarkably large spin splitting of 120 meV. Our results establish NiTe2 as an exciting candidate for next-generation spintronics devices.