The ligand rearrangement reaction of Cr(CO)6 is studied in a series of alcohol solutions using ultafast, infrared spectroscopy and Brownian dynamics simulations.
The photochemistry of the trimetal cluster,Ru(3)(CO)12, was investigated on the ultrafast timescale using UV-vis pump, infrared probe spectroscopy in order to study the transient intermediates formed upon photoexcitation.