- Pisoni, A;
- Jacimovic, J;
- Náfrádi, B;
- Szirmai, P;
- Spina, M;
- Gaál, R;
- Holczer, K;
- Tutis, E;
- Forró, L;
- Horváth, E
The intrinsic d.c. electrical resistivity ($\rho$) - measurable on single
crystals only - is often the quantity first revealing the properties of a given
material. In the case of CH$_3$NH$_3$PbI$_3$ perovskite measuring $\rho$ under
white light illumination provides insight into the coexistence of extended and
shallow localized states (0.1 eV below the conduction band). The former ones
dominate the electrical conduction while the latter, coming from neutral
defects, serve as a long-lifetime charge carrier reservoir accessible for
charge transport by thermal excitation. Remarkably, in the best crystals the
electrical resistivity shows a metallic behaviour under illumination up to room
temperature, giving a new dimension to the material in basic physical studies.