The magnetic, thermal, and transport properties of single crystals of the narrow gap semiconductor Ce3 Au3 Sb4 have been studied. Transport data are consistent with an exponential activation and variable range hopping at low temperatures, which is characteristic of weak disorder and localization. The specific heat and the magnetic susceptibility data suggest the existence of a large density of states of localized states in the gap. The physics is then different from standard Kondo insulators. From its unique physical properties, we propose a three band model (valence, conduction, and f bands) with weak disorder that explains most of the experimental findings. © 2007 The American Physical Society.

Fabrication of epitaxial FeSe_xTe_1-x thin films using pulsed laser deposition (PLD) enables improving their superconducting transition temperature (T _c) by more than ~40% than their bulk T _c. Intriguingly, T _c enhancement in FeSe_xTe_1-x thin films has been observed on various substrates and with different Se content, x. To date, various mechanisms for T _c enhancement have been reported, but they remain controversial in universally explaining the T _c improvement in the FeSe_xTe_1-x films. In this report, we demonstrate that the controversies over the mechanism of T _c enhancement are due to the abnormal changes in the chalcogen ratio (Se:Te) during the film growth and that the previously reported T _c enhancement in FeSe_0.5Te_0.5 thin films is caused by a remarkable increase of Se content. Although our FeSe_xTe_1-x thin films were fabricated via PLD using a Fe_0.94Se_0.45Te_0.55 target, the precisely measured composition indicates a Se-rich FeSe_xTe_1-x (0.6 < x < 0.8) as ascertained through accurate compositional analysis by both wavelength dispersive spectroscopy (WDS) and Rutherford backscattering spectrometry (RBS). We suggest that the origin of the abnormal composition change is the difference in the thermodynamic properties of ternary FeSe_xTe_1-x, based on first principle calculations.