Recent renewed interest in the mixed valent insulator SmB6 comes from topological theory predictions and surface transport measurements of possible in-gap surface states whose existence is most directly probed by angle-resolved photoemission spectroscopy (ARPES). Early photoemission leading up to a recent flurry of ARPES studies of in-gap states is reviewed. Conflicting interpretations about the nature of the Sm 4f-5d hybridization gap and observed X-point bands between the f-states and the Fermi level are critically assessed using the important tools of photon polarization and spatial dependence which also provide additional insight into the origin of the more ambiguous {\Gamma}-point in-gap states.

The thermoelectric performance of SnSe strongly depends on its low-energy electron band structure that provides high density of states in a narrow energy window due to the multi-valley valence band maximum (VBM). Angle-resolved photoemission spectroscopy measurements, in conjunction with first-principles calculations, reveal that the binding energy of the VBM of SnSe is tuned by the population of Sn vacancy, which is determined by the cooling rate during the sample growth. The VBM shift follows precisely the behavior of the thermoelectric power factor, while the effective mass is barely modified upon changing the population of Sn vacancies. These findings indicate that the low-energy electron band structure is closely correlated with the high thermoelectric performance of hole-doped SnSe, providing a viable route toward engineering the intrinsic defect-induced thermoelectric performance via the sample growth condition without an additional ex-situ process.

The interaction between a magnetic impurity, such as cerium (Ce) atom, and surrounding electrons has been one of the core problems in understanding many-body interaction in solid and its relation to magnetism. Kondo effect, the formation of a new resonant ground state with quenched magnetic moment, provides a general framework to describe many-body interaction in the presence of magnetic impurity. In this Letter, a combined study of angle-resolved photoemission (ARPES) and dynamic mean-field theory (DMFT) on Ce-intercalated graphene shows that Ce-induced localized states near Fermi energy, E_F, hybridized with the graphene π-band, exhibit gradual increase in spectral weight upon decreasing temperature. The observed temperature dependence follows the expectations from the Kondo picture in the weak coupling limit. Our results provide a novel insight how Kondo physics emerges in the sea of two-dimensional Dirac electrons.

Corrections to the original paper are the following: Page 692, line 6, left column. "centered at Λ (-0.5 eV < E < 0)" should be "centered at Λ (E < -1 eV)". Page 692, line 2, right column. "E ∼ -0.5 eV" should be "V ∼ +0.6 V".

We present the electronic characterization of single-layer 1H-TaSe₂ grown by molecular beam epitaxy using a combined angle-resolved photoemission spectroscopy, scanning tunneling microscopy/spectroscopy, and density functional theory calculations. We demonstrate that 3 × 3 charge-density-wave (CDW) order persists despite distinct changes in the low energy electronic structure highlighted by the reduction in the number of bands crossing the Fermi energy and the corresponding modification of Fermi surface topology. Enhanced spin-orbit coupling and lattice distortion in the single-layer play a crucial role in the formation of CDW order. Our findings provide a deeper understanding of the nature of CDW order in the two-dimensional limit.