Quantum annealers require accurate control and optimized operation schemes to reduce noise levels, in order to eventually demonstrate a computational advantage over classical algorithms. We study a high coherence four-junction capacitively shunted flux qubit (CSFQ), using dispersive measurements to extract system parameters and model the device. Josephson junction asymmetry inherent to the device causes a deleterious nonlinear cross-talk when annealing the qubit. We implement a nonlinear annealing path to correct the asymmetry in situ, resulting in a substantial increase in the probability of the qubit being in the correct state given an applied flux bias. We also confirm the multi-level structure of our CSFQ circuit model by annealing it through small spectral gaps and observing quantum signatures of energy level crossings. Our results demonstrate an anneal-path correction scheme designed and implemented to improve control accuracy for high-coherence and high-control quantum annealers, which leads to an enhancement of success probability in annealing protocols.