Fire whirls are powerful, spinning disasters for people and surroundings when they occur in large urban and wildland fires. Whereas fire whirls have been studied for fire-safety applications, previous research has yet to harness their potential burning efficiency for enhanced combustion. This article presents laboratory studies of fire whirls initiated as pool fires, but where the fuel sits on a water surface, suggesting the idea of exploiting the high efficiency of fire whirls for oil-spill remediation. We show the transition from a pool fire, to a fire whirl, and then to a previously unobserved state, a "blue whirl." A blue whirl is smaller, very stable, and burns completely blue as a hydrocarbon flame, indicating soot-free burning. The combination of fast mixing, intense swirl, and the water-surface boundary creates the conditions leading to nearly soot-free combustion. With the worldwide need to reduce emissions from both wanted and unwanted combustion, discovery of this state points to possible new pathways for reduced-emission combustion and fuel-spill cleanup. Because current methods to generate a stable vortex are difficult, we also propose that the blue whirl may serve as a research platform for fundamental studies of vortices and vortex breakdown in fluid mechanics.

The relative influence of circulation and buoyancy on fire whirls (FWs), blue whirls (BWs), and the transition between these regimes of a whirling flame is investigated using a combination of experimental data and scaling analyses. FWs are whirling, turbulent, cylindrical yellow (sooting) flame structures that form naturally in fires and are here created in laboratory experiments. In contrast, a BW is a laminar, blue flame (nonsooting) with an inverted conical shape. Measurements of the circulation and heat-release rate are combined with measurements of the flame geometry, defined by the flame width and the height, to provide characteristic length scales for these whirling-flame regimes. Using these, a nondimensional circulation (Γf) and a heat-release rate (Qf) were defined and shown to correspond to azimuthal and axial (buoyancy driven) momenta, respectively. The ratio R=Γf/Qf, a quantity analogous to the swirl number used to characterize swirling jets, was evaluated for FWs and BWs. For FWs, R<1, so that axial momentum is greater than azimuthal momentum and the flame is dominated by buoyant momentum. For BWs, R>1, so that the flame is circulation dominated. This is argued to be consistent with vortex breakdown being an important part of the transition of FWs to BWs. This work presents a basis for predicting when a BW will form and remain a stable regime.

In-situ burning (ISB) is one of the most effective means of removing oil spilled over open water. While current ISB practices can eliminate a large fraction of the spilled oil, they still result in significant airborne emissions of particulate matter. ISBs are classified as large, free-buoyant pool fires, from which black smoke consisting of particulate matter (PM, soot) emanates as a plume. An experimental investigation of soot emissions from pool fires (PF) and fire whirls (FW) was conducted using liquid hydrocarbon fuels, n-heptane and Alaska North Slope (ANS) crude oil, in fuel pools 10−70 cm in diameter. Burning attributes such as burning rate, fuel-consumption efficiency, and emissions of PM, unburned hydrocarbons, carbon dioxide, and oxygen consumption were measured. For both fuels and all pool diameters, compared to PFs, FWs consumed fuel at a higher rate, had lower post-combustion residual mass and PM emission rates. Collectively, these resulted in consistently lower PM emission factors (EFPM) for FWs at all scales. For FWs, EFPM decreased linearly with a nondimensional quantity defined as the ratio of inverse Rossby number to nondimensional heat-release rate. These results show that the addition of ambient circulation to free-burning PFs to form FWs can increase burning efficiency, reducing both burning duration and EFPM across length scales. The reduction in EFPM with increasing influence of circulation is attributed to a feedback loop of higher temperatures, heat feedback, burning rate and air-entrainment velocity, which in turn contributes to maintaining the structure of a FW. Boilover was observed for fires formed with ANS crude oil at the 70 cm scale, although the overall EFPM was not affected significantly. This investigation presents a foundation to evaluate the detailed mechanisms further, such that appropriate configurations can be developed help minimize the environmental impact of ISBs.