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Article
Peer Reviewed

Synthesis, structure and reactivity of Fe II/III –NH 3 complexes bearing a tripodal sulfonamido ligand

Sickerman, Nathaniel S;
Peterson, Sonja M;
Ziller, Joseph W;
Borovik, AS

UC Irvine Previously Published Works (2014)

Complexes [M(n)MST(NH3)](n-3) (M(n) = Fe(II), Fe(III), Ga(III)) were prepared and each contains an intramolecular hydrogen bonding network involving the ammonia ligand. Deprotonation of the Fe(III)-NH3 complex afforded a putative [Fe(III)MST(NH2)](-) species whose reactivity has been explored.

Cover page: Synthesis, structure and reactivity of Fe II/III –NH 3 complexes bearing a tripodal sulfonamido ligand