In ventilation ducts the turbulent flow profile is commonly disturbed or not fully developed, and these conditions are likely to influence particle deposition to duct surfaces. Particle deposition rates at eight S-connectors, in two 90 degrees duct bends and in two ducts where the turbulent flow profile was not fully developed were measured in a laboratory duct system with both bare steel and internally insulated ducts with hydraulic diameters of 15.2 cm. In the bare-steel duct system, experiments with nominal particle diameters of 1, 3, 5, 9, and 16 mu m were conducted at each of three nominal air speeds: 2.2, 5.3, and 9.0 m/s. In the insulated duct system, deposition of particles with nominal diameters of 1, 3, 5, 8, and 13 mu m was measured at nominal air speeds of 2.2, 5.3 and 8.8 m/s. Fluorescent techniques were used to measure directly the deposition velocities of monodisperse fluorescent particles to duct surfaces. Deposition at S-connectors, in bends, and in straight ducts with developing turbulence was often greater than deposition in straight ducts with fully developed turbulence for equal particle sizes, air speeds, and duct surface orientations. Deposition rates at all locations were found to increase with an increase in particle size or air speed. High deposition rates at S-connectors resulted from impaction, and these rates were nearly independent of the orientation of the S-connector. Deposition rates in the two 90 degrees bends differed by more than an order of magnitude in some cases, probably because of the difference in turbulence conditions at the bend inlets. In straight sections of bare steel ducts where the turbulent flow profile was developing, the deposition enhancement relative to fully developed turbulence generally increased with air speed and decreased with downstream distance from the duct inlet. This enhancement was greater at the duct ceiling and wall than at the duct floor. In insulated ducts, deposition enhancement was less pronounced overall than in bare steel ducts. Trends that were observed in bare steel ducts were present, but weaker, in insulated ducts.