- Song, Yekai;
- Jia, Chunjing;
- Xiong, Hongyu;
- Wang, Binbin;
- Jiang, Zhicheng;
- Huang, Kui;
- Hwang, Jinwoong;
- Li, Zhuojun;
- Hwang, Choongyu;
- Liu, Zhongkai;
- Shen, Dawei;
- Sobota, Jonathan A;
- Kirchmann, Patrick;
- Xue, Jiamin;
- Devereaux, Thomas P;
- Mo, Sung-Kwan;
- Shen, Zhi-Xun;
- Tang, Shujie
The excitonic insulator (EI) is a Bose-Einstein condensation (BEC) of excitons bound by electron-hole interaction in a solid, which could support high-temperature BEC transition. The material realization of EI has been challenged by the difficulty of distinguishing it from a conventional charge density wave (CDW) state. In the BEC limit, the preformed exciton gas phase is a hallmark to distinguish EI from conventional CDW, yet direct experimental evidence has been lacking. Here we report a distinct correlated phase beyond the 2×2 CDW ground state emerging in monolayer 1T-ZrTe2 and its investigation by angle-resolved photoemission spectroscopy (ARPES) and scanning tunneling microscopy (STM). The results show novel band- and energy-dependent folding behavior in a two-step process, which is the signatures of an exciton gas phase prior to its condensation into the final CDW state. Our findings provide a versatile two-dimensional platform that allows tuning of the excitonic effect.