Undisturbed grasslands can sequester significant quantities of organic carbon (OC) in soils. Irrigation and fertilization enhance CO₂sequestration in managed turfgrass ecosystems but can also increase emissions of CO₂ and other greenhouse gases (GHGs). To better understand the GHG balance of urban turf, we measured OC sequestration rates and emission of N₂O (a GHG ∼ 300 times more effective than CO₂) in Southern California, USA. We also estimated CO₂ emissions generated by fuel combustion, fertilizer production, and irrigation. We show that turf emits significant quantities of N₂O (0.1–0.3 g N m⁻² yr⁻¹) associated with frequent fertilization. In ornamental lawns this is offset by OC sequestration (140 g C m⁻² yr⁻¹), while in athletic fields, there is no OC sequestration because of frequent surface restoration. Large indirect emissions of CO₂ associated with turfgrass management make it clear that OC sequestration by turfgrass cannot mitigate GHG emissions in cities.

Nitrous oxide (N₂O) is a powerful greenhouse gas increasing in atmospheric mixing ratio and linked to increasing amounts of reactive N in the environment, particularly fertilizer use in agriculture. The consequences of urbanization of agricultural land for global and regional N₂O emissions are unclear, due to high spatial and temporal variability of fluxes from different ecosystems and relatively few studies of urban ecosystems. We measured fluxes and the stable isotope composition (δ ¹⁵N and δ ¹⁸O) of N₂O over 1 year in urban (ornamental lawns and athletic fields) and agricultural (corn and vegetable fields) ecosystems near Los Angeles, California, United States. We found that urban landscapes (lawns and athletic fields) have annual N₂O fluxes equal to or greater than agricultural fields. Fertilization rates of urban landscapes were equal to or greater than agricultural fields, with comparable N₂O emissions factors. δ ¹⁵N and δ ¹⁸O of N₂O varied widely in all ecosystems, and were not consistent with ecosystem type, season, soil moisture, or temperature. There was, however, a consistent response of δ ¹⁵N-N₂O to pulses of N₂O emission following fertilization, with an initial depletion in δ ¹⁵N relative to prefertilization values, then gradual enrichment to background values within about 1 week. Preliminary scaling calculations indicated that N₂O emissions from urban landscapes are approximately equal to or greater than agricultural emissions in urbanized areas of southern California, which further implies that current estimates of regional N₂O emissions (based on agricultural land area) may be too low.

A growing dependence on natural gas for energy may exacerbate emissions of the greenhouse gas methane (CH4). Identifying fingerprints of these emissions is critical to our understanding of potential impacts. Here, we compare stable isotopic and alkane ratio tracers of natural gas, agricultural, and urban CH4 sources in the Barnett Shale hydraulic fracturing region near Fort Worth, Texas. Thermogenic and biogenic sources were compositionally distinct, and emissions from oil wells were enriched in alkanes and isotopically depleted relative to natural gas wells. Emissions from natural gas production varied in δ(13)C and alkane ratio composition, with δD-CH4 representing the most consistent tracer of natural gas sources. We integrated our data into a bottom-up inventory of CH4 for the region, resulting in an inventory of ethane (C2H6) sources for comparison to top-down estimates of CH4 and C2H6 emissions. Methane emissions in the Barnett are a complex mixture of urban, agricultural, and fossil fuel sources, which makes source apportionment challenging. For example, spatial heterogeneity in gas composition and high C2H6/CH4 ratios in emissions from conventional oil production add uncertainty to top-down models of source apportionment. Future top-down studies may benefit from the addition of δD-CH4 to distinguish thermogenic and biogenic sources.

Oil and natural gas operations have continued to expand and move closer to densely populated areas, contributing to growing public concerns regarding exposure to hazardous air pollutants. During the Barnett Shale Coordinated Campaign in October, 2013, ground-based whole air samples collected downwind of oil and gas sites revealed enhancements in several potentially toxic volatile organic compounds (VOCs) when compared to background values. Molar emissions ratios relative to methane were determined for hexane, benzene, toluene, ethylbenzene, and xylene (BTEX compounds). Using methane leak rates measured from the Picarro mobile flux plane (MFP) system and a Barnett Shale regional methane emissions inventory, the rates of emission of these toxic gases were calculated. Benzene emissions ranged between 51 ± 4 and 60 ± 4 kg h^-1. Hexane, the most abundantly emitted pollutant, ranged from 642 ± 45 to 1070 ± 340 kg h^-1. While observed hydrocarbon enhancements fall below federal workplace standards, results may indicate a link between emissions from oil and natural gas operations and concerns about exposure to hazardous air pollutants. The larger public health risks associated with the production and distribution of natural gas are of particular importance and warrant further investigation, particularly as the use of natural gas increases in the United States and internationally.

In this study, we present seasonal atmospheric measurements of δ13CCH4 from dairy farms in the San Joaquin Valley of California. We used δ13CCH4 to characterize emissions from enteric fermentation by measuring downwind of cattle housing (e.g., freestall barns, corrals) and from manure management areas (e.g., anaerobic manure lagoons) with a mobile platform equipped with cavity ring-down spectrometers. Across seasons, the δ13CCH4 from enteric fermentation source areas ranged from −69.7 ± 0.6 per mil (‰) to −51.6 ± 0.1‰ while the δ13CCH4 from manure lagoons ranged from −49.5 ± 0.1‰ to −40.5 ± 0.2‰. Measurements of δ13CCH4 of enteric CH4 suggest a greater than 10‰ difference between cattle production groups in accordance with diet. Isotopic signatures of CH4 were used to characterize enteric and manure CH4 from downwind plume sampling of dairies. Our findings show that δ13CCH4 measurements could improve the attribution of CH4 emissions from dairy sources at scales ranging from individual facilities to regions and help constrain the relative contributions from these different sources of emissions to the CH4 budget.

Climate-sensitive Arctic lakes have been identified as conduits for ancient permafrost-carbon (C) emissions and as such accelerate warming. However, the environmental factors that control emission pathways and their sources are unclear; this complicates upscaling, forecasting and climate-impact-assessment efforts. Here we show that current whole-lake CH4 and CO2 emissions from widespread lakes in Arctic Alaska primarily originate from organic matter fixed within the past 3-4 millennia (modern to 3,300 ± 70 years before the present), and not from Pleistocene permafrost C. Furthermore, almost 100% of the annual diffusive C flux is emitted as CO2. Although the lakes mostly processed younger C (89 ± 3% of total C emissions), minor contributions from ancient C sources were two times greater in fine-textured versus coarse-textured Pleistocene sediments, which emphasizes the importance of the underlying geological substrate in current and future emissions. This spatially extensive survey considered the environmental and temporal variability necessary to monitor and forecast the fate of ancient permafrost C as Arctic warming progresses.

Global atmospheric concentrations of methane (CH4), a powerful greenhouse gas, are increasing, but because there are many natural and anthropogenic sources of CH4, it is difficult to assess which sources may be increasing in magnitude. Here we present a data set of δ2H-CH4 measurements of individual sources and air in the Colorado Front Range, USA. We show that δ2H-CH4, but not δ13C, signatures are consistent in air sampled downwind of landfills, cattle feedlots, and oil and gas wells in the region. Applying these source signatures to air in ground and aircraft samples indicates that at least 50% of CH4 emitted in the region is biogenic, perhaps because regulatory restrictions on leaking oil and natural gas wells are helping to reduce this source of CH4. Source apportionment tracers such as δ2H may help close the gap between CH4 observations and inventories, which may underestimate biogenic as well as thermogenic sources.