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Local Structure of La1-xSrxCoO3 determined from EXAFS and neutron PDF studies
Abstract
The combined local structure techniques, extended x-ray absorption fine structure (EXAFS) and neutron pair distribution function analysis, have been used for temperatures 4 <= T <= 330 K to rule out a large Jahn-Teller (JT) distortion of the Co-O bond in La1?xSrxCoO3 for a significant fraction of Co sites (x <= 0.35), indicating few, if any, JT-active, singly occupied eg Co sites exist.
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