Skip to main content
eScholarship
Open Access Publications from the University of California

Ferrocene-bis(phosphinimine) Nickel(II) and Palladium(II) Alkyl Complexes: Influence of the Fe-M (M = Ni and Pd) Interaction on Redox Activity and Olefin Coordination

  • Author(s): Abubekerov, M
  • Khan, SI
  • Diaconescu, PL
  • et al.
Abstract

© 2017 American Chemical Society. The synthesis of several novel nickel(II) and palladium(II) ferrocene-bis(phosphinimine) alkyl complexes containing iron-nickel and iron-palladium interactions is reported. The redox behavior of all complexes was evaluated electrochemically and chemically; in addition, reactions with weak nucleophiles, such as acetonitrile and olefins, were also investigated. DFT calculations were performed to understand the electronic structure of the alkyl metal complexes.

Many UC-authored scholarly publications are freely available on this site because of the UC Academic Senate's Open Access Policy. Let us know how this access is important for you.

Main Content
Current View