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Diels-Alder construction of regiodifferentiated meta-amino phenols and derivatives.

  • Author(s): Weaver, Marisa G
  • Bai, Wen-Ju
  • Jackson, Stephen K
  • Pettus, Thomas RR
  • et al.

Published Web Location

https://doi.org/10.1021/ol4034447
Abstract

Synthetic access to regiodifferentiated meta-amino phenols is described. The strategy relies upon distinct deprotonation conditions to afford regioisomeric thermodynamic and kinetic dienes that undergo a tandem Diels-Alder and retro-Diels-Alder sequence with assorted acetylenic dienophiles to afford a range of aromatic products.

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