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A Biomimetic Synthesis of des-Hydroxy Paecilospirone
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https://doi.org/10.1055/s-0036-1592001Abstract
The carbon framework of des-hydroxy paecilospirone was rapidly synthesized using a biomimetic approach whereby an enol ether and an ortho-quinone methide (o-QM), each derived from the same lactone, were combined to arrive at the complete carbon skeleton of paecilospirone.
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