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Rapid Synthesis of Fused Oxabicycles through the Molecular Rearrangement of Spirocyclic Ethers

  • Author(s): Palmer, Leoni I
  • Veits, Gesine K
  • Read de Alaniz, Javier
  • et al.
Abstract

A molecular rearrangement of 5,5-spirocyclic cyclopentenones to 5,6-fused cyclopentenones catalyzed by Amberlyst®15 is described. This work emphasizes the utility of renewable resources, such as furfural, that can be transformed into a variety of valuable products. It also highlights the viability of 5,5-spirocycles as intermediates en route to 5,6-fused cyclopentenones. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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