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Ex situ NMR relaxometry of metal-organic frameworks for rapid surface-area screening.

  • Author(s): Chen, Joseph J
  • Kong, Xueqian
  • Sumida, Kenji
  • Manumpil, Mary Anne
  • Long, Jeffrey R
  • Reimer, Jeffrey A
  • et al.
Abstract

Taking a relaxed approach: The NMR relaxation behavior of imbibed solvent has been used to estimate the surface area of a variety of microporous metal-organic frameworks and zeolites. This NMR technique is amenable to automation and can expedite the characterization of microporous materials by identifying any nonporous or low-surface-area structures. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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