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Diastereoselective Coupling of Chiral Acetonide Trisubstituted Radicals with Alkenes.

  • Author(s): Tao, Daniel J
  • Muuronen, Mikko
  • Slutskyy, Yuriy
  • Le, Alexander
  • Furche, Filipp
  • Overman, Larry E
  • et al.
Abstract

The stereochemical outcome of reactions of chiral nucleophilic trisubstituted acetonide radicals with electron-deficient alkenes is dictated by a delicate balance between destabilizing non-bonding interactions and stabilizing hydrogen-bonding between substituents on the α and β carbons.

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