Cation distribution in a Fe-bearing K-feldspar from Itrongay, Madagascar. A combined neutron- and X-ray single crystal diffraction study
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Cation distribution in a Fe-bearing K-feldspar from Itrongay, Madagascar. A combined neutron- and X-ray single crystal diffraction study

  • Author(s): Ackermann, Sonia
  • Kunz, Martin
  • Armbruster, Thomas
  • Schefer, Jurg
  • Hanni, Henry
  • et al.
Abstract

We determined the cation distribution and ordering of Si, Al and Fe on the tetrahedral sites of a monoclinic low-sanidine from Itrongay, Madagascar, by combined neutron- and X-ray single-crystal diffraction. The cation distribution was determined by means of a simultaneous refinement using neutron- and X-ray data, as well as by combining scattering densities obtained from separate refinements with chemical data from a microprobe experiment. The two methods give the same results and show that Fe is fully ordered on T1, whereas Al shows a high degree of disorder. Based on this and previously published temperature-dependent X-ray data, we conclude that it is preferential ordering of Fe on T1 even at high temperature, rather than a high diffusion kinetics of Fe, which causes this asymmetry in ordering behaviour between Al and Fe. The preferential ordering of Fe3+ relative to Al3+ in T1 is consistent with its 25 percent larger ionic radius.

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