Lawrence Berkeley National Laboratory
Three-Dimensional Visualization of Conductive Domains in Battery Electrodes with Contrast-Enhancing Nanoparticles
- Author(s): Morelly, Samantha L
- Gelb, Jeff
- Iacoviello, Francesco
- Shearing, Paul R
- Harris, Stephen J
- Alvarez, Nicolas J
- Tang, Maureen H
- et al.
Published Web Locationhttps://doi.org/10.1021/acsaem.8b01184
Copyright © 2018 American Chemical Society. Replacing conductive carbon black with commercial carbon-coated iron nanoparticles yields an effective contrast-enhancing agent to differentiate between active material, conductive additive, and binder in lithium-ion battery electrodes. Nano-XCT resolved the carbon-binder domain with 126 nm voxel resolution, showing partial coatings around the active material particles and interparticle bridges. In a complementary analysis, SEM/EDS determined individual distributions of conductive additives and binder. Surprisingly, the contrast-enhancing agents showed that the effect of preparation parameters on the heterogeneity of conductive additives was weaker than on the binder. Incorporation of such contrast-enhancing additives can improve understanding of processing-structure-function relationships in a multitude of devices for energy conversion and storage.