Direct synthesis of Z-alkenyl halides through catalytic cross-metathesis

2016

Published Web Location

https://doi.org/10.1038/nature17396

Abstract

One shortcoming of olefin metathesis has been that acyclic alkenyl halides could not be generated efficiently and stereoselectively; but now halo-substituted molybdenum alkylidene species are shown to be able to participate in high-yielding olefin metathesis reactions that afford acyclic 1,2-disubstituted Z-alkenyl halides.

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Direct synthesis of Z-alkenyl halides through catalytic cross-metathesis

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