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Bandgap Tunability in Sb‐Alloyed BiVO4 Quaternary Oxides as Visible Light Absorbers for Solar Fuel Applications
Published Web Location
https://onlinelibrary.wiley.com/doi/full/10.1002/adma.201502361No data is associated with this publication.
Abstract
The challenge of fine compositional tuning and microstructure control in complex oxides is overcome by developing a general two-step synthetic approach. Antimony-alloyed bismuth vanadate, which is identified as a novel light absorber for solar fuel applications, is prepared in a wide compositional range. The bandgap of this quaternary oxide linearly decreases with the Sb content, in agreement with first-principles calculations.