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Spectroscopic Studies of Electronic States in Unconventional Superconductors

Abstract

This work will present experimental results on two projects measuring the electronic properties of unconventional superconductors. The first project focuses on the iron-based superconductor system of FeSe1-xSx. We used scanning tunneling microscopy/spectroscopy (STM/S) to make detailed measurements of the electronic states of tetragonal FeSe0.89S 0.19. We also performed theoretical band structure calculations that were calibrated by angle-resolved photoemission spectroscopy measurements for comparison. We utilize the high spatial resolution of the STM/S measurements to separately analyze modulations in the local density of states (LDOS) in regions near and away from iron-vacancies. This analysis revealed two types of features: (i) energy dispersive quasiparticle interference patterns which can explained by our band structure calculations and (ii) a much stronger modulation just above the Fermi level centered at q=0.12 Å-1 which does not disperse with energy and cannot be explained by our band structure model. Local rotational symmetry analysis shows that while the modulations are four-fold symmetric on average, they are actually comprised of small domains with two-fold symmetry. Statistical analysis demonstrates that the boundaries of these domains are spatially correlated with the locations of iron-vacancies.

The second project studies charge order in the La-based cuprate La1.475Nd0.4Sr0.125CuO4. We performed temperature and uniaxial strain dependent resonant x-ray scattering studies on the charge order and the low-temperature orthorhombic to low-temperature tetragonal (LTO-LTT) structural transition. Before applying any strain, we found a precursor charge order peak existing up to 200 K, well above the static charge order onset temperature. Upon applying uniaxial tensile strain of about 0.1%, we observed a reduction in the onset of charge order by 50 K and a 20 K reduction in the LTO-LTT transition temperature. We also saw a preference for the charge order to form in the direction of applied strain due to a 6 K difference in onset temperatures for the two directions.

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