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Open Access Publications from the University of California

Atomically thin two-dimensional organic-inorganic hybrid perovskites.

  • Author(s): Dou, Letian
  • Wong, Andrew B
  • Yu, Yi
  • Lai, Minliang
  • Kornienko, Nikolay
  • Eaton, Samuel W
  • Fu, Anthony
  • Bischak, Connor G
  • Ma, Jie
  • Ding, Tina
  • Ginsberg, Naomi S
  • Wang, Lin-Wang
  • Alivisatos, A Paul
  • Yang, Peidong
  • et al.

Organic-inorganic hybrid perovskites, which have proved to be promising semiconductor materials for photovoltaic applications, have been made into atomically thin two-dimensional (2D) sheets. We report the solution-phase growth of single- and few-unit-cell-thick single-crystalline 2D hybrid perovskites of (C4H9NH3)2PbBr4 with well-defined square shape and large size. In contrast to other 2D materials, the hybrid perovskite sheets exhibit an unusual structural relaxation, and this structural change leads to a band gap shift as compared to the bulk crystal. The high-quality 2D crystals exhibit efficient photoluminescence, and color tuning could be achieved by changing sheet thickness as well as composition via the synthesis of related materials.

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