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Poly[[tri - Cyanido-cyanido(1,4,10,13-tetra-oxa-7,16-diaza-cyclo-octa-deca- ne)barium(II)platinum(II)] hemihydrate]

  • Author(s): Olmstead, MM
  • Beavers, CM
  • Paw U, L
  • et al.
Abstract

The title compound, {[BaPt(CN)4(C12H 26N2O4)]·0.5H2O} n , is a two-dimensional coordination polymer in which the sheets are oriented approximately parallel to the ( 01) set of crystal planes. In the crystal structure, disordered water mol-ecules (half occupancy) connect the sheets into a three-dimensional network via inter-molecular O - H⋯O hydrogen bonds. An N - H⋯N inter-action is also present. The shortest Pt⋯Pt contacts are 7.5969 (4) Å by an inversion relationship and 7.6781 (4) Å by translation along the a axis.

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