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P4 Activation by Lanthanum and Lutetium Naphthalene Complexes Supported by a Ferrocene Diamide Ligand

Published Web Location

https://doi.org/10.1002/ejic.201300225
Abstract

Two rare-earth (La and Lu) naphthalene complexes supported by a ferrocene diamide ligand activate P4 under ambient conditions to form M 3P7 species exclusively. The resulting complexes feature a Zintl-type polyphosphide P73- unit stabilized by three lanthanide fragments. The reported metal complexes were characterized by X-ray crystallography, multinuclear NMR spectroscopy, and elemental analysis. © 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

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