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P4activation by lanthanum and lutetium naphthalene complexes supported by a ferrocene diamide ligand

  • Author(s): Huang, W
  • Diaconescu, PL
  • et al.
Abstract

Two rare-earth (La and Lu) naphthalene complexes supported by a ferrocene diamide ligand activate P4under ambient conditions to form M3P7species exclusively. The resulting complexes feature a Zintl-type polyphosphide P73-unit stabilized by three lanthanide fragments. The reported metal complexes were characterized by X-ray crystallography, multinuclear NMR spectroscopy, and elemental analysis. © 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

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