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Anisotropic phase segregation and migration of Pt in nanocrystals en route to nanoframe catalysts

Published Web Location

https://doi.org/10.1038/nmat4724
Abstract

Compositional heterogeneity in shaped, bimetallic nanocrystals offers additional variables to manoeuvre the functionality of the nanocrystal. However, understanding how to manipulate anisotropic elemental distributions in a nanocrystal is a great challenge in reaching higher tiers of nanocatalyst design. Here, we present the evolutionary trajectory of phase segregation in Pt-Ni rhombic dodecahedra. The anisotropic growth of a Pt-rich phase along the 〈111〉 and 〈200〉 directions at the initial growth stage results in Pt segregation to the 14 axes of a rhombic dodecahedron, forming a highly branched, Pt-rich tetradecapod structure embedded in a Ni-rich shell. With longer growth time, the Pt-rich phase selectively migrates outwards through the 14 axes to the 24 edges such that the rhombic dodecahedron becomes a Pt-rich frame enclosing a Ni-rich interior phase. The revealed anisotropic phase segregation and migration mechanism offers a radically different approach to fabrication of nanocatalysts with desired compositional distributions and performance.

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