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Open Access Publications from the University of California

Relativistic effects in metallocorroles: Comparison of molybdenum and tungsten biscorroles

  • Author(s): Alemayehu, AB
  • Vazquez-Lima, H
  • McCormick, LJ
  • Ghosh, A
  • et al.

© 2017 The Royal Society of Chemistry. The homoleptic sandwich compounds-Mo and W biscorroles-have afforded a novel platform for experimental studies of relativistic effects. A 200 mV difference in reduction potential and a remarkable 130 nm shift of a near-IR spectral feature have been identified as manifestations of relativistic effects on the properties of these complexes.

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