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Catalytic Alkyne Arylation Using Traceless Directing Groups

Published Web Location

https://doi.org/10.1002/anie.201804955
Abstract

By using Pd0 /Mandyphos, we achieved a three-component aminoarylation of alkynes to generate enamines, which are then hydrolyzed to either α-arylphenones or α,α-diarylketones. This Pd-catalyzed method overcomes established known pathways to enable the use of amines as traceless directing groups for C-C bond formation.

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