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Enantiospecific Total Synthesis of N‐Methylwelwitindolinone D Isonitrile
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https://doi.org/10.1002/anie.201307464Abstract
The total synthesis of N-methylwelwitindolinone D isonitrile (1) has been achieved in 17 steps from a readily available carvone derivative. The route features a double C-H functionalization event involving a keto oxindole substrate to introduce the tetrahydrofuran ring of the natural product.
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