Lithium Ethylene Dicarbonate Identified as the Primary Product of Chemical and
Electrochemical Reduction of EC in EC:EMC/1.2M LiPF6 Electrolyte
- Author(s): Zhuang, Guorong V.;
- Xu, Kang;
- Yang, Hui;
- Jow, T. Richard;
- Ross Jr., Philip N.
- et al.
Lithium ethylene dicarbonate (CH2OCO2Li)2 was chemically synthesized and its Fourier Transform Infrared (FTIR) spectrum was obtained and compared with that of surface films formed on Ni after cyclic voltammetry (CV) in 1.2M lithium hexafluorophosphate (LiPF6)/ethylene carbonate (EC): ethyl methyl carbonate (EMC) (3:7, w/w) electrolyte and on metallic lithium cleaved in-situ in the same electrolyte. By comparison of IR experimental spectra with that of the synthesized compound, we established that the title compound is the predominant surface species in both instances. Detailed analysis of the IR spectrum utilizing quantum chemical (Hartree-Fock) calculations indicates that intermolecular association through O. . .Li. . .O interactions is very important in this compound. It is likely that the title compound in passivation layer has a highly associated structure, but the exact intermolecular conformation could not be established based on analysis of the IR spectrum.