Three-dimensional attosecond resonant stimulated X-ray Raman spectroscopy of electronic excitations in core-ionized glycine.
- Author(s): Zhang, Yu;
- Biggs, Jason D;
- Hua, Weijie;
- Dorfman, Konstantin E;
- Mukamel, Shaul
- et al.
Published Web Locationhttps://doi.org/10.1039/c4cp03361b
We investigate computationally the valence electronic excitations of the amino acid glycine prepared by a sudden nitrogen core ionization induced by an attosecond X-ray pump pulse. The created superposition of cationic excited states is probed by two-dimensional transient X-ray absorption and by three dimensional attosecond stimulated X-ray Raman signals. The latter, generated by applying a second broadband X-ray pulse combined with a narrowband pulse tuned to the carbon K-edge, reveal the complex coupling between valence and core-excited manifolds of the cation.