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Nanoporous gold assemblies of calixarene-phosphine-capped colloids.

  • Author(s): Schöttle, Christian
  • Clark, Ezra L
  • Harker, Audrey
  • Solovyov, Andrew
  • Bell, Alexis T
  • Katz, Alexander
  • et al.
Abstract

The synthesis of high surface-area colloidal assemblies of calixarene-phosphine-capped nanoporous gold is reported under reductive electrochemical conditions. These materials uniquely exhibit a remarkably thin wall thickness down to 10 nm, while possessing pore sizes on the order of up to hundreds of nanometers, which can be controlled via choice of organic ligand.

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