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Nanoporous gold assemblies of calixarene-phosphine-capped colloids

  • Author(s): Schöttle, C
  • Clark, EL
  • Harker, A
  • Solovyov, A
  • Bell, AT
  • Katz, A
  • et al.
Abstract

© 2017 The Royal Society of Chemistry. The synthesis of high surface-area colloidal assemblies of calixarene-phosphine-capped nanoporous gold is reported under reductive electrochemical conditions. These materials uniquely exhibit a remarkably thin wall thickness down to 10 nm, while possessing pore sizes on the order of up to hundreds of nanometers, which can be controlled via choice of organic ligand.

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