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Synthesis and characterization of a polyoxovanadate cluster representing a new topology.

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https://doi.org/10.1039/b507531aCreative Commons 'BY' version 4.0 license
Abstract

A new type of mixed-valence polyoxoanionic cluster, [V(V)13V(IV)3O42(Cl)]8-, composed of 14 {VO5} square pyramids and 2 {VO4} tetrahedral units, hosting a chloride ion has been synthesized and characterized.

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