Lawrence Berkeley National Laboratory

To extend organoactinide chemistry beyond uranium, reported here is the first structurally characterized transuranic hydrocarbyl complex, Np[η⁴ -Me₂ NC(H)C₆ H₅ ]₃ (1), from reaction of NpCl₄ (DME)₂ with four equivalents of K[Me₂ NC(H)C₆ H₅ ]. Unlike the U^III species, the neptunium analogue can be used to access other Np^III complexes. The reaction of 1 with three equivalents of HE₂ C(2,6-Mes₂ -C₆ H₃ ) (E=O, S) yields [(2,6-Mes₂ -C₆ H₃ )CE₂ ]₃ Np(THF)₂ , maintaining the trivalent oxidation state.