Effect of Ring Strain on the Charge Transport of a Robust Norbornadiene-Quadricyclane-Based Molecular Photoswitch.
- Author(s): Tebikachew, Behabitu E
- Li, Haipeng B
- Pirrotta, Alessandro
- Börjesson, Karl
- Solomon, Gemma C
- Hihath, Joshua
- Moth-Poulsen, Kasper
- et al.
Published Web Locationhttps://doi.org/10.1021/acs.jpcc.7b00319
Integrating functional molecules into single-molecule devices is a key step toward the realization of future computing machines based on the smallest possible components. In this context, photoswitching molecules that can make a transition between high and low conductivity in response to light are attractive candidates. Here we present the synthesis and conductance properties of a new type of robust molecular photothermal switch based on the norbornadiene (NB)-quadricyclane (QC) system. The transport through the molecule in the ON state is dominated by a pathway through the π-conjugated system, which is no longer available when the system is switched to the OFF state. Interestingly, in the OFF state we find that the same pathway contributes only 12% to the transport properties. We attribute this observation to the strained tetrahedral geometry of the QC. These results challenge the prevailing assumption that current will simply flow through the shortest through-bond path in a molecule.