Imaging the internal electronic structure of a surface adsorbate with low energy ions
- Author(s): Yarmoff, Jory A
- Yang, Y
- Sroubek, Z
- et al.
Time-of-flight spectra were collected for 2.5 keV Li-7(+) backscattered from Fe surfaces covered with submonolayers of iodine. Li singly scattered from the adatoms has a consistently larger neutral fraction than for scattering from the substrate, implying a region of positive charge atop the iodine. The neutral fraction decreases for off-normal exit angles, indicating a nonuniform charge distribution around the polarizable adsorbates. This demonstrates that ion scattering can image the internal electronic structure of an adatom and provides an explanation for anomalous work function changes.
Many UC-authored scholarly publications are freely available on this site because of the UC Academic Senate's Open Access Policy. Let us know how this access is important for you.