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The debut of chiral cyclic (alkyl)(amino)carbenes (CAACs) in enantioselective catalysis
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https://doi.org/10.1039/c9sc02810bAbstract
The popularity of NHCs in transition metal catalysis has prompted the development of chiral versions as electron-rich neutral stereodirecting ancillary ligands for enantioselective transformations. Herein we demonstrate that cyclic (alkyl)(amino)carbene (CAAC) ligands can also engage in asymmetric transformations, thereby expanding the toolbox of available chiral carbenes.
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