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Synthesis, structure and reactivity of Fe II/III –NH 3 complexes bearing a tripodal sulfonamido ligand
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https://doi.org/10.1039/c3cc48804gAbstract
Complexes [M(n)MST(NH3)](n-3) (M(n) = Fe(II), Fe(III), Ga(III)) were prepared and each contains an intramolecular hydrogen bonding network involving the ammonia ligand. Deprotonation of the Fe(III)-NH3 complex afforded a putative [Fe(III)MST(NH2)](-) species whose reactivity has been explored.
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