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Intrinsic chemical reactivity of solid-electrolyte interphase components in silicon-lithium alloy anode batteries probed by FTIR spectroscopy

  • Author(s): Pekarek, Ryan T;
  • Affolter, Alec;
  • Baranowski, Lauryn L;
  • Coyle, Jaclyn;
  • Hou, Tingzheng;
  • Sivonxay, Eric;
  • Smith, Brenda A;
  • McAuliffe, Rebecca D;
  • Persson, Kristin A;
  • Key, Baris;
  • Apblett, Christopher;
  • Veith, Gabriel M;
  • Neale, Nathan R
  • et al.
Abstract

The chemical reactivity of silicon surface species with LiPF6/carbonate electrolyte are detailed via FTIR spectroscopy and verified by MD/DFPD simulations.

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