Crystal growth, structure, magnetic, and transport properties of TbRhln5
- Author(s): Williams, WM
- Pham, L
- MaQuilon, S
- Moldovan, M
- Fisk, Z
- Young, DP
- Chan, JY
- et al.
Published Web Locationhttps://doi.org/10.1021/ic060185w
Single crystals of TbRhln5 were synthesized using the flux growth method. TbRhln5 adopts the HoCoGa5 structure type and crystallizes in the space group P4/mmm, Z = 1. Lattice parameters are a = 4.6000(6) Å, c = 7.4370(11) Å, and V = 157.29(6) Å3. Transport measurements show that TbRhln5 is metallic (dρ/dT > 0). A sharp antiferromagnetic transition is observed at TN = 48 K in the susceptibility data for TbRhln5, which is highly anisotropic when the field is oriented along the c axis and a-b plane of the crystal and has an average effective moment of 9.72 μB/ Tb3+. © 2006 American Chemical Society.
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