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The Low Basicity of Phosphabenzenes: First Examples of Protonation, Alkylation, and Silylation Reactions
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https://doi.org/10.1002/anie.200800878Abstract
(Figure Presented) Strong yet gentle: Where triflate reagents fail, carborane-based sources of H+, CH3+, and [R3Si]+ electrophiles add to phosphabenzenes preferentially at the P atom rather than C (see picture). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
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